Alcohols Phenols And Ethers Question 110

Question: Dehydration of alcohols by conc. $ H_2SO_4 $ takes place according to following steps: The slowest and fastest steps in the above reaction are

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Options:

A) step 1 is slowest, while 3 is fastest.

B) step 2 is slowest, while 3 is fastest.

C) step 2 is slowest, while 4 is fastest.

D) all steps proceed at equal rate.

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Step 2 involves the formation of carbonium ion by the loss of weakly basic $H _{2}O$ molecule. It is slowest step. Step 4 involves the conversion of an unstable (or intermediate) into a quite stable product, hence it is fastest step.