Alcohols Phenols And Ethers Question 116

Question: Correct increasing order of acidity is as follows

Options:

A) $ H_2O,C_2H_2,H_2CO_3 $ , phenol

B) $ C_2H_2,H_2O,H_2CO_3 $ , phenol

C) phenol, $ C_2H_2,H_2CO_3,H_2O $

D) $ C_2H_2,H_2O $ , phenol, $ ,H_2CO_3 $

Show Answer

Answer:

Correct Answer: D

Solution:

[d] Such questions can be solved by considering the relative basic character of their conjugated bases which for $ H_2O,C_2H_2,H_2CO_3 $ and $ C_6H_5OH $ are $ ^{-}OH,HC\equiv {C^{-}}:,HCO_3^{-},C_6H_5{O^{-}} $ More the possibility for the dispersal of the negative charge, weaker will be the base. Thus the relative basic character of the four bases is Thus the acidic character of the four corresponding acids will be $ H_2CO_3>C_6H_5OH>H_2O>HC\equiv CH $