Alcohols Phenols And Ethers Question 120

Question: Arrange the following in increasing order of their acidity- [a] o-cresol, [b] salicylic acid, [c] phenol

Options:

A) $ c \lt a \lt b $

B) $ b \lt c \lt a $

C) $ a \lt b \lt a $

D) $ a \lt c \lt b $

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Answer:

Correct Answer: D

Solution:

[d] Electron releasing groups $ (-CH_3,-OCH_3,-NCH_3etc) $ intensify the negative charge of phenoxide ion, i.e., destablises it hence decreases ionization of parent phenol, therefore decreases acidity. While electron withdrawing groups $ ( -NO_2\text{,}-COOH,-CHOetc. ) $ increases acidity.