Alcohols Phenols And Ethers Question 135

Question: The $ -OH $ group of methyl alcohol cannot be replaced by chlorine by the action of

[KCET 1989]

Options:

A) Chlorine

B) Hydrogen chloride

C) Phosphorus trichloride

D) Phosphorus pentachloride

Show Answer

Answer:

Correct Answer: A

Solution:

$ CH_3OH+Cl_2\to Noreaction $

$ CH_3OH+HCl\xrightarrow{ZnCl_2}CH_3Cl+H_2O $

$ 3CH_3OH+PCl_3\to 3CH_3Cl+H_3PO_3 $

$ CH_3OH+PCl_5\to CH_3Cl+POCl_3+HCl $