Alcohols Phenols And Ethers Question 172

Question: Propene, $ CH_3-CH=CH_2 $ can be converted to 1-propanol by oxidation. Which set of reagents among the following is ideal to effect the conversion

[CBSE PMT 1991]

Options:

A) Alkaline $ KMnO_4 $

B) $ B_2H_6 $ and alkaline $ H_2O_2 $

C) $ O_3/Zn $ dust

D) $ OsO_4/CH_4,Cl_2 $

Show Answer

Answer:

Correct Answer: B

Solution:

Hydroboration oxidation (Industrial preparation of alcohol) $ 3CH_3CH=CH_2+\frac{1}{2}B_2H_6\underset{ether}{\mathop{\xrightarrow{Dry}}}{{(CH_3CH_2CH_3)}_3}B $

$ {{(CH_3CH_2CH_3)}_3}B\xrightarrow{H_2O_2}3CH_3CH_2CH_2-OH $