Alcohols Phenols And Ethers Question 191

Question: $ C_2H_5MgI $ reacts with HCHO to form last product

[MP PMT 1991]

Options:

A) $ CH_3CHO $

B) $ C_3H_7OH $

C) $ CH_3COCH_3 $

D) $ CH_3COOCH_3 $

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Answer:

Correct Answer: B

Solution:

$ \begin{matrix} H \\ H \\ \end{matrix}>C=O+C_2H_5MgI\to \underset{\underset{C_2H_5}{\mathop{|}}}{\mathop{CH_2-}}O-MgI $

$ \xrightarrow{Hydrolysis}C_2H_5-CH_2-OH $ or $ {C_3}H_7OH+Mg<\begin{matrix} I \\ OH \\ \end{matrix} $