Alcohols Phenols And Ethers Question 223

Question: On heating glycerol with conc. $ H_2SO_4, $ a compound is obtained which has a bad odour. The compound is

[CPMT 1974; CBSE PMT 1994]

Options:

A) Glycerol sulphate

B) Acrolein

C) Formic acid

D) Allyl alcohol

Show Answer

Answer:

Correct Answer: B

Solution:

$ \underset{CH_2-OH}{\overset{CH_2-OH}{\mathop{\underset{|}{\overset{|}{\mathop{CH}}}-OH}}}\underset{H_2SO_4}{\mathop{\xrightarrow{conc\text{.}}}}\underset{Acrolein}{\mathop{\underset{CHO}{\overset{CH_2}{\mathop{\underset{|}{\overset{||}{\mathop{CH}}}}}}}}+2H_2O $