Alcohols Phenols And Ethers Question 229

Question: Glycerol was distilled with oxalic acid crystals and the products were led into Fehling solution and warmed. Cuprous oxide was precipitated. It is due to

[KCET 1987]

Options:

A) CO

B) HCHO

C) $ CH_3CHO $

D) HCOOH

Show Answer

Answer:

Correct Answer: D

Solution:

$ HOOC-COOH\underset{Decarboxylation}{\mathop{\xrightarrow{Glycerol}}}HCOOH+CO_2 $

$ HCOOH+Fehlingsolution\to \underset{Redppt\text{.}}{\mathop{Cu_2O}}+CO_2+H_2O $