Alcohols Phenols And Ethers Question 234

Question: Primary and secondary alcohols on action of reduced copper give

[CPMT 1982; MP PMT 1985; EAMCET 1987, 93; MP PET 1995]

Options:

A) Aldehydes and ketones respectively

B) Ketones and aldehydes respectively

C) Only aldehydes

D) Only ketones

Show Answer

Answer:

Correct Answer: A

Solution:

$ \underset{1^{o}alcohol}{\mathop{R\text{-}CH_2OH}}\xrightarrow{Cu}R-CHO+H_2 $

$ \underset{2^{o}alcohol}{\mathop{R-\underset{OH}{\mathop{\underset{|}{\mathop{CH}}}}-R}}\xrightarrow{Cu}R-\underset{O}{\mathop{\underset{||}{\mathop{C}}}}-R+H_2 $