Alcohols Phenols And Ethers Question 258

Question: Carbylamine test is done by heating alcoholic KOH with

[IIT-JEE 1984; BIT 1992; CBSE PMT 1992]

Options:

A) Chloroform and silver powder

B) Trihalogen methane and primary amine

C) Alkyl halide and primary amine

D) Alkyl cyanide and primary amine

Show Answer

Answer:

Correct Answer: B

Solution:

Carbylamine reaction $ CHCl_3+CH_3NH_2+\underset{alc\text{.}}{\mathop{3KOH}}\to \underset{\begin{smallmatrix} \text{Methyl } \\ isocyanide \end{smallmatrix}}{\mathop{CH_3N\vec{=}}}\underset{{}}{\mathop{C+3KCl+3H_2O}} $