Alcohols Phenols And Ethers Question 260

Question: Isopropyl alcohol heated at $ 300^{o}C $ with copper catalyst to form

[AFMC 1990; MP PMT 1986, 89, 92; JIPMER 2000]

Options:

A) Acetone

B) Dimethyl ether

C) Acetaldehyde

D) Ethane

Show Answer

Answer:

Correct Answer: A

Solution:

Secondary alcohol on dehydrogenation gives acetone $ CH_3-\underset{\underset{OH}{\mathop{|}}}{\mathop{CH}}-CH_3\underset{300^{0}C}{\mathop{\xrightarrow{Cu}}}CH_3-\underset{\underset{O}{\mathop{||}}}{\mathop{C}}-CH_3+H_2 $