Alcohols Phenols And Ethers Question 27

Question: Which of the following compound give yellow precipitate with $ I_2 $ and NaOH

[Pb. CET 2003]

Options:

A) $ CH_3OH $

B) $ CH_3CH_2CH_2OH $

C) $ C_2H_5OC_2H_5 $

D) $ CH_3CH_2OH $

Show Answer

Answer:

Correct Answer: D

Solution:

Ethyl alcohol give positive iodoform test (i.e. yellow ppt. with $ I_2 $ and NaOH) $ CH_3CH_2OH+4I_2+6NaOH\to $

$ \underset{\text{yellow ppt}\text{.}}{\mathop{CHI_3}}+5NaI+CH_3COONa+3H_2O $