Alcohols Phenols And Ethers Question 289

Question: Glycerol reacts with conc. $ HNO_3 $ and conc. $ H_2SO_4 $ to form

[CPMT 1983; MP PMT/PET 1988]

Options:

A) Glycerol mononitrate

B) Glycerol dinitrate

C) Glycerol trinitrate

D) Acrolein

Show Answer

Answer:

Correct Answer: C

Solution:

$ \underset{CH_2-OH}{\overset{CH_2-OH}{\mathop{\underset{|}{\overset{|}{\mathop{CH-OH}}}}}}+3HNO_3\underset{H_2SO_4}{\mathop{\xrightarrow{Conc\text{.}H_2SO_4}}}\underset{Glyceroltrinitrate}{\mathop{\underset{CH_2-ONO_2}{\overset{CH_2-ONO_2}{\mathop{\underset{|}{\overset{|}{\mathop{CH}}}-ONO_2}}}}}+3H_2O $