Alcohols Phenols And Ethers Question 59

Question: Rate of dehydration of alcohols follows the order:

Options:

A) $ 2{}^\circ >1{}^\circ >CH_3OH>3{}^\circ $

B) $ 3{}^\circ >2{}^\circ >1{}^\circ >CH_3OH $

C) $ 2{}^\circ >3{}^\circ >1{}^\circ >CH_3OH $

D) $ CH_3OH>1{}^\circ >2{}^\circ >3{}^\circ $

Show Answer

Answer:

Correct Answer: B

Solution:

[b] The order of dehydration among three type of alcohols is $ 3{}^\circ >2{}^\circ >1{}^\circ >CH_3OH $ . This behaviour is related to the relative stabilities of carbocations $ ( 3{}^\circ >2{}^\circ >1{}^\circ ). $