Alcohols Phenols And Ethers Question 70

Question: Which one of the following substituents at para- position is most effective in stabilizing the Product of the reaction is:

Options:

A) $ -CH_3 $

B) $ -OCH_3 $

C) $ -COCH_3 $

D) $ -CH_2OH $

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Answer:

Correct Answer: C

Solution:

[c] Electron withdrawing group stabilises the benzene ring due to delocalisation of charge. $ -CH_3 $ and $ -CH_2OH $ are electron donating group and hence decrease the stability of benzene ring $ -OCH_3 $ is weaker electron withdrawing group than- $ -COCH_3 $ . Hence $ -COCH_3 $ group more stabilize the phenoxide ion at p-position.