Alcohols Phenols And Ethers Question 75

Question: Which is the best reagent to convert isopropyl alcohol to isopropyl bromide- $ CH_3-\overset{CH_3}{\mathop{\overset{|}{\mathop{C}}}}H-OH\xrightarrow{-}CH_3-\overset{CH_3}{\mathop{\overset{|}{\mathop{C}}}}H-Br $

Options:

A) $ HBr $

B) $ SOBr_2 $

C) $ Br_2 $

D) $ CH_3MgBr $

Show Answer

Answer:

Correct Answer: B

Solution:

[b] $ CH_3-\overset{CH_3}{\mathop{\overset{|}{\mathop{C}}}}H-OH\xrightarrow{SOBr_2} $

$ CH_3-\overset{CH_3}{\mathop{\overset{|}{\mathop{C}}}}H-Br+SO_2+HBr $ Side products are gases. In case of $ HBr $ elimination also favours to produce alkene.