Alcohols Phenols And Ethers Question 78

Question: On reaction with sodium, 1 mol of a compound X gives 1 mol of $ H_2 $ Which one of the following compounds might be X-

Options:

A) $ CH_3CH_2CH=CH_2 $

B) $ CH_3COOCH_2CH_3 $

C) $ CH_3CH_2CH_2OH $

D) $ CH_2(OH)CH_2CH_2CH_2OH $

Show Answer

Answer:

Correct Answer: D

Solution:

[d] Since 1 mole of compound X reacts with Na to evolve 1 mole of $ H_2 $ gas, therefore the compound should have 2 active hydrogen atoms per mole which is possible only in option d. $ CH_2OHCH_2CH_2OH+2Na\xrightarrow{{}} $

$ NaOCH_2CH_2CH_2CH_2ONa+2H $