Alcohols Phenols And Ethers Question 94

Question: Which of the following reactions will not result in the formation of anisole-

Options:

A) Phenol + dimethyl sulphate in presence of a base

B) Sodium phenoxide is treated with methyl iodide

C) Reaction of diazomethane with phenol

D) Reaction of methylmagnesium iodide with phenol

Show Answer

Answer:

Correct Answer: D

Solution:

[d] Phenol has active (acidic) hydrogen so it reacts with $ CH_3MgI $ to give $ CH_4, $ and not anisole $ C_6H_5OH+CH_3MgI\xrightarrow{{}}CH_4+C_6H_5OMgI $