Aldehydes Ketones Question 118

Question: $ C_2H_5CHO $ and $ {{(CH_3)}_2}CO $ can be distinguished by testing with

[EAMCET 1998; CPMT 1994, 97; MP PET 1995; MP PMT 1996; RPMT 1997, 99]

Options:

A) Phenyl hydrazine

B) Hydroxylamine

C) Fehling solution

D) Sodium bisulphite

Show Answer

Answer:

Correct Answer: C

Solution:

$ C_2H_5CHO+2C{u^{+2}}+5O{H^{-}}\to \underset{Redppt}{\mathop{Cu_2O}}+3H_2O $

$ +C_2H_5CO{O^{-}} $

$ CH_3COCH_3+2C{u^{+2}}+5O{H^{-}}\to Noreaction $