Aldehydes Ketones Question 138

Question: Acetaldehyde and acetone differ in their reaction with

[KCET 1989]

Options:

A) Sodium bisulphite

B) Ammonia

C) Phosphorus pentachloride

D) Phenyl hydrazine

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Answer:

Correct Answer: B

Solution:

$ CH_3-\underset{O}{\mathop{\underset{||}{\mathop{C}}}}-H+NH_3\to CH_3-\underset{NH_2}{\overset{OH}{\mathop{\underset{|}{\overset{|}{\mathop{C-H}}}}}} $

$ 2CH_3-\underset{O}{\mathop{\underset{||}{\mathop{C}}}}-CH_3+NH_3\to CH_3-\underset{NH_2}{\overset{CH_3}{\mathop{\underset{|}{\overset{|}{\mathop{C-}}}}}}CH_2\overset{O}{\mathop{\overset{||}{\mathop{-C}}}}-CH_3 $