Aldehydes Ketones Question 139

Question: The appropriate reagent for the transformation

[IIT-JEE (Screening) 2000]

Options:

A) $ Zn(Hg),HCl $

B) $ NH_2NH_2O{H^{-}} $

C) $ H_2/Ni $

D) $ NaBH_4 $

Show Answer

Answer:

Correct Answer: B

Solution:

Both $ Zn(Hg),HCl $ and $ NH_2NH_2,O{H^{-}} $ can reduce $ -COCH_3 $ group to $ -CH_2-CH_3 $ group, but HCl will also bring about dehydration of alcohol to form alkene. Therefore, appropriate reagent for the conversion is $ NH_2NH_2,O{H^{-}} $ .