Aldehydes Ketones Question 154

Question: Propanal on treatment with dilute sodium hydroxide forms

[Kerala CET 2000]

Options:

A) $ CH_3CH_2CH_2CH_2CH_2CHO $

B) $ CH_3CH_2CH(OH)CH_2CH_2CHO $

C) $ CH_3CH_2CH(OH)CH(CH_3)CHO $

D) $ CH_3CH_2COONa $

Show Answer

Answer:

Correct Answer: C

Solution:

$ CH_3CH_2-\underset{H}{\overset{O}{\mathop{\underset{|}{\overset{||}{\mathop{C}}}}}}\bullet +H\underset{CH_3}{\mathop{\underset{|}{\overset{\alpha }{\mathop{CH}}}}}-CHO\xrightarrow{O{H^{-}}} $

$ CH_3-CH_2-\overset{OH}{\mathop{\overset{|}{\mathop{CH}}}}-\underset{CH_3}{\mathop{\underset{|}{\mathop{CHCHO}}}} $