Aldehydes Ketones Question 182

Question: Which one of the following on oxidation will not give a carboxylic acid with the same number of carbon atoms

[CBSE PMT 1992; MP PET 1996]

Options:

A) $ CH_3COCH_3 $

B) $ CCl_3CH_2CHO $

C) $ CH_3CH_2CH_2OH $

D) $ CH_3CH_2CHO $

Show Answer

Answer:

Correct Answer: A

Solution:

$ CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}-CH_3}}\underset{H_2SO_4}{\mathop{\xrightarrow{K_2Cr_2O_7}}}CH_3COOH+HCOOH $ one carbon atom is less in the ketone group