Aldehydes Ketones Question 2

Question: Enol content is highest in

[Orissa JEE 2005]

Options:

A) Acetone

B) Acetophenone

C) Acetic acid

D) Acetyl acetone

Show Answer

Answer:

Correct Answer: D

Solution:

The amount of enolic form is highest (76%) in acetyl acetone because keto group is a much better electron-withdrawing group. $ \overset{{}}{\longleftrightarrow}\overset{O….HO}{\mathop{\overset{|||}{\mathop{CH_3C-CH=C-CH_3}}}} $