Aldehydes Ketones Question 21

Question: Which of the following on oxidation followed by hydrolysis gives pyruvic acid-

Options:

A) Acetaldehyde cyanohydrin

B) Acetone cyanohydrin

C) Formaldehyde cyanohydrin

D) None of these

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Answer:

Correct Answer: A

Solution:

[a] $ \underset{Acetaldehydecyanohydrin}{\mathop{CH_3\overset{OH}{\mathop{\overset{|}{\mathop{C}}}}HCN}}~\xrightarrow{[O]}CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-CN $

$ \xrightarrow{{H^{+}},H_2O}CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-COOH $