Aldehydes Ketones Question 22

Question: Identify the correct order of boiling points of the following compounds:

$ \underset{1}{\mathop{CH_3CH_2CH_2OH}} $
$ \underset{2}{\mathop{CH_3CH_2CH_2CHO}} $ $ \underset{3}{\mathop{CH_3CH_2CH_2COOH}} $

Options:

A) 1>2>3

B) 3>1>2

C) 1>3>2

D) 3>2>1

Show Answer

Answer:

Correct Answer: B

Solution:

[b] Due to -I effect of the -COOH group, H-bonds in acids are much stronger than in alcohols; while aldehydes do not exhibit H-bonding.