Aldehydes Ketones Question 222

Question: Which of the following will not give butyl acetate when treated with 1-butanol

Options:

A) $ CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-Cl( pyridene ) $

B) $ CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-OH( H_2SO_4 ) $

C) $ CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-O-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-CH_3( pyridene ) $

D) $ CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-H( H_2SO_4 ) $

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Answer:

Correct Answer: D

Solution:

[d] Acid chlorides, anhydrides, acids give ester with alcohol $ ROH+R’COCI\xrightarrow{{}}ROCOR’+HCl $

$ ROH+{{( R’CO )}_2}O\xrightarrow{{}}ROCOR’+RCOOH $

$ ROH+{R}‘COOH\xrightarrow{{}}ROCO{R}’+H_2O $