Aldehydes Ketones Question 52

Question: Among the following the order of reactivity towards nucleophilic addition is

Options:

A) $ CH_3CHO>CH_3COCH_3>HCHO $

B) $ HCHO>CH_3CHO>CH_3COCH_3 $

C) $ CH_3CHO>HCHO>CH_3COCH_3 $

D) $ CH_3COCH_3>CH_3CHO>HCHO $

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Answer:

Correct Answer: B

Solution:

[b] Presence of alkyl group in carbonyl compounds decreases their reactivity towards nucleophilic addition. Further greater the number of such groups lesser will be the reactivity towards nucleophilic addition
$ \therefore $ correct order is $ HCHO>CH_3CHO>CH_3COCH_3 $