Aldehydes Ketones Question 60

Question: Reaction of acetaldehyde with HCN followed by hydrolysis gives a compound which shows

[MP PET 1997]

Options:

A) Optical isomerism

B) Geometrical isomerism

C) Metamerism

D) Tautomerism

Show Answer

Answer:

Correct Answer: A

Solution:

$ \underset{Acetaldehyde}{\mathop{CH_3-\overset{O}{\mathop{\overset{||}{\mathop{C}}}}-H}}+\underset{\begin{smallmatrix} Hydrogen \\ Cyanide \end{smallmatrix}}{\mathop{HCN}}\xrightarrow{{}}\underset{\begin{smallmatrix} Acetaldehyde \\ Cynohydrin \end{smallmatrix}}{\mathop{\overset{OH}{\mathop{\overset{|}{\mathop{\underset{CN}{\mathop{\underset{|}{\mathop{CH_3-C-H}}}}}}}}}} $ (Optically active)