Aldehydes Ketones Question 89

Question: Which alkene is formed from the following reaction $ CH_3CH_2CH_2CH=PPh_3+2-Butanone $

[Manipal 2001]

Options:

A) 3- Methyl-3-heptene

B) 4-Methyl-3-heptene

C) 5-Methyl-3-heptene

D) 1-Methyl-5- methane

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Answer:

Correct Answer: A

Solution:

$ \underset{2-Butanone}{\mathop{CH_3CH_2-\overset{CH_3}{\mathop{\overset{|}{\mathop{C}}=O}}}}+CH_3CH_2CH_2CH=PPh_3 $

$ \to \underset{3-\text{methyl,}3-heptene}{\mathop{CH_3CH_2\overset{CH_3}{\mathop{\overset{|}{\mathop{C=}}C}}HCH_2CH_2CH_3+Ph_3PO}} $