Aldehydes Ketones Question 94

Question: On heating calcium acetate and calcium formate, the product formed is

[DPMT 1984; EAMCET 1985; MP PMT 1996, 92; KCET 1990; CPMT 1979, 82, 84; BIT 1992; RPET 2000]

Options:

A) $ CH_3COCH_3 $

B) $ CH_3CHO $

C) $ HCHO+CaCO_3 $

D) $ CH_3CHO+CaCO_3 $

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Answer:

Correct Answer: D

Solution:

$ \begin{matrix} CH_3COO \\ CH_3COO \\ \end{matrix}>Ca+Ca<\begin{matrix} OOCH \\ OOCH \\ \end{matrix}\xrightarrow{Distill} $

$ 2CH_3CHO+2CaCO_3 $