Nitrogen Containing Compounds Question 108

Question: Unpleasant smelling carbylamines are formed by heating alkali and chloroform with [KCET 1987, 2000, 01]

Options:

A) Any amine

B) Any aliphatic amine

C) Any aromatic amine

D) Any primary amine

Show Answer

Answer:

Correct Answer: D

Solution:

$ R-NH_2+CHC{l_{,3}}+3NaOH\to RN\vec{=}C+3NaCl+3H_2O $ The unpleasant smell is due to the formation of isocyanides.