Nitrogen Containing Compounds Question 150

Question: When acetamide reacts with $ Br_2 $ and caustic soda, then we get : [CPMT 2004]

Options:

A) Acetic acid

B) Bromoacetic acid

C) Methyl amine

D) Ethyl amine

Show Answer

Answer:

Correct Answer: C

Solution:

This is Hofman-bromide reaction. In this reaction one carbon less amines are formed from amides. $ CH_3CONH_2\xrightarrow{Br_2/KOH}CH_3NH_2 $