Nitrogen Containing Compounds Question 23

Question: An organic compound ‘A’ $ (C_3H_9N) $ reacts with benzene sulphonyl chloride to give a solid insoluble in alkali. The structure of ‘A’ is

Options:

A) $ CH_3NHC_2H_5 $

B) $ {{(CH_3)}_3}N $

C) $ CH_3CH_2CH_2NH_2 $

D) insufficient data to predict

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Answer:

Correct Answer: A

Solution:

[a] Benzene-sulphony1 chloride (Hinsberg reagent) yields a solid insoluble in alkali with secondary amines.