Nitrogen Containing Compounds Question 29

Question: Arrange the following compounds in decreasing order of coupling with benzenediazonium chloride.

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Options:

A) IV>I>II>III

B) II>I>IV>III

C) II>IV>I>III

D) II>III>IV>I

Show Answer

Answer:

Correct Answer: C

Solution:

[c] Coupling reaction between arenediazonium cation and an aromatic compounds which bear powerful electron-releasing groups like $ -OH,-NH_2,-NHR, $ or $ -NR_2 $ , hence toluene, having weak electron-releasing $ -CH_3 $ group cannot couple with diazonium cation.