Nitrogen Containing Compounds Question 32

Question: In the diazotization of aniline with sodium nitrite and hydrochloric acid, an excess of hydrochloric acid is used primarily to:

Options:

A) suppress the concentration of free aniline available for coupling

B) suppress hydrolysis of phenol

C) insure a stoichiometric amount of nitrous acid

D) neutralize the base liberated

Show Answer

Answer:

Correct Answer: A

Solution:

[a] In diazotization of aniline with $ NaNO_2 $ and HCl an excess of HCl is used to suppress the concentration of aniline available for coupling.