Nitrogen Containing Compounds Question 38

Question: Amides may be converted into amines by reaction named after [CPMT 1974; MP PET 1992; CBSE PMT 1999]

Options:

A) Perkin

B) Claisen

C) Hoffmann

D) Kolbe

Show Answer

Answer:

Correct Answer: C

Solution:

Hofmann?s bromamide reaction $ \underset{Acetamide}{\mathop{CH_3-CO-NH_2}},+Br_2+4KOH\xrightarrow{H_2O} $ $ \underset{Methylamine}{\mathop{CH_3NH_2}},+K_2CO_3+2KBr+2H_2O $