Nitrogen Containing Compounds Question 40

Question: Acetamide is treated separately with the following reagents. Which would give methyl amine [IIT 1983; CPMT 1988, 94; MP PET 1993; MP PMT 1996; AIIMS 1998]

Options:

A) $ PCl_5 $

B) $ NaOH+Br_2 $

C) Sodalime

D) Hot conc. $ H_2SO_4 $

Show Answer

Answer:

Correct Answer: B

Solution:

$ \underset{Acetamide}{\mathop{CH_3CONH_2}},+Br_2+4NaOH\to $ $ \underset{\text{Methyl amine}}{\mathop{CH_3NH_2}},+Na_2CO_3+2NaBr+2H_2O $