Analytical Chemistry Question 106

Question: A mixture containing $ C{d^{2+}} $ and $ HCl( 6N ) $ can be separated for identification by

[MP PMT 1994]

Options:

A) Passing $ Hg_2Cl_2 $ in acid medium

B) Passing $ PbCl_2 $ in alkaline medium

C) Passing $ PbCl_2 $ in neutral medium

D) Passing $ HgCl_2 $ in dry mixture

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Answer:

Correct Answer: A

Solution:

$ C{u^{2+}} $ will be precipitated as CuS in acidic medium where as $ N{i^{2+}} $ is not precipitated.