Analytical Chemistry Question 120

Question: The presence of $ NH_4Cl $ in the test solution while precipitating group III-A hydroxides (in qualitative inorganic analysis) helps in

Options:

A) Lowering $ [ O{H^{-}} ] $

B) Lowering $ [ NH_4OH ] $

C) Increasing $ [ O{H^{-}} ] $

D) Increasing $ [ NH_4OH ] $

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Answer:

Correct Answer: A

Solution:

$ NH_4OH~NH_4^{+}+O{H^{-}} $

$ NH_4Cl\to NH_4^{+}+C{l^{-}} $

$ NH_4Cl $ Decreases the dissociation of $ NH_4OH $ by common ion effect