Analytical Chemistry Question 155

Question: Sodium sulphite on heating with dilute $ HCl $ liberates a gas which

[NCERT 1972]

Options:

A) Turns lead acetate paper black

B) Turns acidified potassium dichromate paper green

C) Burns with a blue flame

D) Smells like vinegar

Show Answer

Answer:

Correct Answer: B

Solution:

$ Na_2S+dil\text{.2}HCl\to 2NaCl+H_2S $

$ H_2S\ +\ H_2SO_4\ +\ K_2Cr_2O_7\ \xrightarrow{acidic}\ K_2SO_4 $

$ +\ \underset{\text{(green)}}{\mathop{Cr_2{{(SO_4)}_3}}}\ +\ S $