Analytical Chemistry Question 157

Question: A red solid is insoluble in water. However it becomes soluble if some KI is added to water. Heating the red solid in a test tube results in liberation of some violet coloured fumes and droplets of a metal appear on the cooler parts of the test tube. The red solid is

[AIEEE 2003]

Options:

A) $ {{( NH_4 )}_2}Cr_2O_7 $

B) $ HgI_2 $

C) $ HgO $

D) $ Pb_3O_4 $

Show Answer

Answer:

Correct Answer: B

Solution:

$ \underset{\text{Red solid}}{\mathop{HgI_2+2K}}I\to K_2(HgI_4) $ soluble $ HgI_2\to Hg+I_2 $ violet foams.