Analytical Chemistry Question 218

Question: In the standardization of $ Na_2S_2O_3 $ using $ K_2Cr_2O_7 $ by iodometry, the equivalent weight of $ K_2Cr_2O_7 $ is

[IIT-JEE (Screening) 2001]

Options:

A) (Molecular weight)/2

B) (Molecular weight)/6

C) (Molecular weight)/3

D) Same as molecular weight

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Answer:

Correct Answer: B

Solution:

Hyposolution are used as the reducing agent with potassium dicromate solution $ \overset{+6}{\mathop{K_2Cr_2O_7}}=\frac{\text{Molecular weight}}{6} $