Analytical Chemistry Question 219

Question: 25 ml of a solution of $ Na_2CO_3 $ having a specific gravity of 1.25 required 32.9 ml of a solution of HCl containing 109.5 grams of the acid per litre for complete neutralization. Calculate the volume of $ 0.84NH_2SO_4 $ that will be completely neutralized by 125 grams of the $ Na_2CO_3 $ solution

[UPSEAT 2001]

Options:

A) 460 ml

B) 540 ml

C) 480 ml

D) 470 ml

Show Answer

Answer:

Correct Answer: D

Solution:

$ N_1V_1=N_2V_2 $

$ N\times 25=\frac{109.5\times 32.9}{36.5} $ Þ $ N=\frac{109.5\times 32.9}{36.5\times 25} $

$ N_3V_3=N_4V_4 $ ( $ V_3=\frac{m}{d} $ , $ V_3=\frac{125}{1.25} $ ) $ \frac{109.5\times 32.9}{36.5\times 25}\times 100=0.84\times V $ Þ $ V=470ml $