Analytical Chemistry Question 262

Question: In the reaction $ I_2+2S_2O_3^{-}\to 2{l^{-}}+S_4O_6^{2-}; $ the equivalent weight of iodine will be equal to

[MNR 1985; UPSEAT 2000]

Options:

A) Molecular weight

B) 1/2 the molecular weight

C) 1/4 the molecular weight

D) Twice the molecular weight

Show Answer

Answer:

Correct Answer: B

Solution:

$ \underset{(O)}{\mathop{I_2}}+2S_2O_3^{-}\to \underset{(-2)}{\mathop{2{I^{-}}}}+S_4O_6^{2-} $
$ \therefore $ Eq. wt. = $ \frac{1}{2}\ \times \ \text{molecular wt}\text{.} $