Analytical Chemistry Question 30

Question: When $ KBr $ is treated with conc. $ H_2SO_4 $ a reddish-brown gas is evolved. The evolved gas is

[EAMCET 1978]

Options:

A) Bromine

B) Mixture of bromine and $ HBr $

C) $ HBr $

D) $ NO_2 $

Show Answer

Answer:

Correct Answer: A

Solution:

$ 2KBr+MnO_2+3H_2SO_4\to MnSO_4+2KHSO_4 $

$ +2H_2O+\underset{\begin{smallmatrix} \text{(reddish} \\ \text{brown gas)} \end{smallmatrix}}{\mathop{Br_2\uparrow }} $