Analytical Chemistry Question 37

Question: $ Na_2CO_3 $ cannot be used to identify

[BVP 2004]

Options:

A) $ CO_3^{2-} $

B) $ SO_3^{2-} $

C) $ {S^{2-}} $

D) $ SO_4^{2-} $

Show Answer

Answer:

Correct Answer: A

Solution:

$ SO_3^{2-},{S^{2-}} $ and $ SO_4^{2-} $ salts from comparatively stronger acids (than $ H_2CO_3) $ in solution hence evolve $ CO_2 $ with $ Na_2CO_3 $ solution and give effervesence. While $ CO_3^{2-} $ does not react with $ Na_2CO_3 $ solution