Analytical Chemistry Question 39

Question: Gas $ A $ is bubbled through slaked lime when a white precipitate is formed. On prolonged bubbling, the precipitate is dissolved. on heating the resultant solution, the white precipitate reappears with the evolution of gas $ B $ . The gases $ A $ and $ B $ respectively are

[DPMT 2004]

Options:

A) $ CO_2 $ and $ CO $

B) $ CO $ and $ CO_2 $

C) $ CO $ and $ CO $

D) $ CO_2 $ and $ CO_2 $

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Answer:

Correct Answer: D

Solution:

According to the equation, $ Ca{{(OH)}_2}+CO_2\xrightarrow{\Delta }CaCO_3+H_2O $

$ CaCO_3+H_2O+CO_2\xrightarrow{{}}Ca{{(HCO_3)}_2} $

$ Ca{{(HCO_3)}_2}\xrightarrow{\Delta }CaO+H_2O+2CO_2 $ Hence, the gas A and B are $ CO_2 $ and $ CO_2 $ respectively