Analytical Chemistry Question 44

Question: When acetic acid and $ K_4Fe{{( CN )}_6} $ is added to a copper salt, a chocolate precipitate is obtained of the compound

Options:

A) Copper cyanide

B) Copper ferrocyanide

C) Basic copper sulphate

D) Basic copper cyanide

Show Answer

Answer:

Correct Answer: B

Solution:

$ Cu{{(NH_3)}_4}{{(NO_3)}_2}+4CH_3COOH\to Cu{{(NO_3)}_2} $

$ +4CH_3COONH_4 $

$ 2Cu{{(NO_3)}_2}+K_4[Fe{{(CN)}_6}]\to \underset{chocolateppt}{\mathop{Cu_2Fe{{(CN)}_6}}} $

$ +4KNO_3 $