Analytical Chemistry Question 48

Question: Conc. $ HNO_3 $ is added before proceeding to test for group III members. This is to

[NCERT 1974]

Options:

A) Oxidise any remaining $ H_2S $

B) Convert ferrous ion into ferric ion

C) Form nitrates which give granular ppts

D) Increase ionisation of ammonium hydroxide

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Answer:

Correct Answer: B

Solution:

HNO3 oxidises $ F{e^{2+}} $ to $ F{e^{3+}} $ otherwise $ F{e^{2+}} $ is not completely precipitated as hydroxide